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Sealed pinholes prolong lifespan of perovskite solar cells

Posted: 04 Jun 2015     Print Version  Bookmark and Share

Keywords:solar cell  perovskite  pinhole  hole transport layer 

Perovskite solar cells that are being developed today suffer from pinhole problems in its top layer, but scientists at the Okinawa Institute of Science and Technology Graduate University (OIST) claim to have found a solution to this obstacle.

The researchers have also improved the lifetime of the solar cell and made it thinner. The findings have been published in Scientific Reports.

The pinholes, identified by OIST's Energy Materials and Surface Sciences Unit led by Prof. Yabing Qi, are located in the top layer of the solar cell, known as the hole transport layer and were identified as a key cause for the quick degradation of perovskite solar cells. Researchers around the world are investigating the potential of perovskite, a manmade organic-inorganic hybrid material, as an alternative to silicon-based solar cells.

"Pinholes are a very critical problem because it is a pathway for moisture and oxygen to attack the perovskite material, which is the active layer converting sunlight to energy," said Min-Cherl Jung, a staff scientist at OIST and first author of this work. "Without pinholes in the hole transport layer, the perovskite is protected and the lifetime improves."

 Spiro-OMeTAD

Many high-performance solar cells under development layer spiro-OMeTAD on top of perovskite, with other trace elements added to increase electrical conductivity.

The researchers eliminated the pinholes by using a different method to create the top layer of the solar cell, which is made of a material called spiro-OMeTAD. Instead of dissolving spiro-OMeTAD powder in a solution and then spin-coating it onto perovskite, they evaporated the powder in a vacuum chamber and the spiro-OMeTAD molecules deposited onto the solar cell.

To create this layer, a solar cell is positioned upside down on the ceiling of a vacuum chamber. As the spiro-OMeTAD is heated up, it evaporates and the gas molecules that stick to the perovskite, creating an even layer—much like when snow blankets the ground. Essentially, the spiro-OMeTAD molecules are snowing, but up rather than down.

"Vacuum evaporation enables us to much more precisely control the deposition rate and thus the thickness of this layer," explained Jung. "We were able to reduce the thickness of the solar cell from over 200nm to 70nm."


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