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Nanoparticle ink to ease manufacturing of flexible devices

Posted: 14 Jul 2014     Print Version  Bookmark and Share

Keywords:National Institute for Materials Science  Okayama University  nanoparticle ink  flexible electronics 

A team of researchers at the National Institute for Materials Science and Okayama University in Japan has developed what they describe as a nanoparticle ink that can be used with room-temperature printing procedures. According to them, the nanoparticle ink can be used for printing electronics without high-temperature annealing, which offers a probable profitable approach for manufacturing flexible electronics.

Printing semiconductor devices is considered to provide low-cost high performance flexible electronics that outperforms the amorphous silicon thin film transistors that presently limits developments in display technology. However the nanoparticle inks developed so far have required annealing, which limits them to substrates that can withstand high temperatures, ruling out a lot of the flexible plastics that could otherwise be used.

Developments in thin film transistors made from amorphous silicon have provided wider, thinner displays with higher resolution and lower energy consumption. However further progress in this field is limited by the low response to applied electric fields, that is, the low field-effect mobility. Oxide semiconductors such as InGaZnO (IGZO) offer better performance characteristics but require complicated fabrication procedures.

Nanoparticle inks should allow simple low-cost manufacture but the nanoparticles usually used are surrounded in non-conductive ligands, molecules that are introduced during synthesis for stabilising the particles. These ligands must be removed by annealing to make the ink conducting. Takeo Minari, Masayuki Kanehara and colleagues found a way around this difficulty by developing nanoparticles surrounded by planar aromatic molecules that allow charge transfer.

The gold nanoparticles had a resistivity of around 9 x 10-6Ωcm, similar to pure gold. The researchers used the nanoparticle ink to print organic thin film transistors on a flexible polymer and a paper substrate at room temperature, producing devices with mobilities of 7.9 and 2.5cm2 V-1 s-1 for polymer and paper respectively, figures comparable to IGZO devices.

Fully printed organic thin film transistors on a paper substrate

Fully printed organic thin film transistors (OTFTs) on a paper substrate. (a) Schematic of the device structure for a fully printed OTFT on paper. (b) Arrays of fully printed OTFTs fabricated on a paper substrate inkjet printed with the NIMS logo before adding the device. (c) An optical microscope image of fully-printed OTFT arrays. (d) A magnified optical microscope image of the individual device. Arrays of fully printed organic thin film transistors fabricated on paper substrates that had the NIMS logo ink jet printed on before processing.





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